Study of no Rydberg states H′2Π-, O′2Π- using two-photon excitation
✍ Scribed by Shuo-Yan Zhao; Shu-Ming Zhang; Ming-Cheng Zhong; Pei-Lin Zhang
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 507 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0022-4073
No coin nor oath required. For personal study only.
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A formalism of MRCPA 4 presented in the recent study of one of the Ž . authors K. T. and Mochizuki is reconsidered and coupling terms which appear in calculating excited states will be improved for the sake of guaranteeing size consistency in case of separating a molecular system into two fragments.
## Quasiclassical trajectory calculations have been carried out for the reaction 0( 'D) +HD( 'Z\* )4OD/OH (%I) +H/D('S) using a two-valued potential energy surface derived by Murrell, Carter, Mills and Guest. The OD/OH branching ratio on this multivalued surface at 300 K is close to 2, and experim