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Study of ionic catalytic systems by the electrodialysis method

✍ Scribed by F. S. Dyachkovskii; E. H. Grigoryan; O. N. Babkina

Publisher
John Wiley and Sons
Year
1981
Tongue
English
Weight
473 KB
Volume
13
Category
Article
ISSN
0538-8066

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✦ Synopsis

A special method of electrodialysis has been developed for investigation of the kinetics and mechanism of polymerization reactions involving ions. The ionic composition of homogeneous systems such as CpzTiRClAlRC12, RTiC13 + AlRC12, Ti(OR)4 + AIRS, and (RLi), has been studied. The composition of catalytically active ions has been determined. Using the regularities of "open" systems, the methods of determining the carbocation reactivity under electrodialysis conditions have been worked out. The impulse electrodialysis method has been suggested for studying ionic polymerization kinetics and evaluating the rate constants of ion reactions with the monomer and gegenion.

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