Dynamic nuclear polarization of tin-l 19 in free radical solutions has been studied at 175 G. Scalar interactions are predominant for both bivalent and tetravalent tin compounds.
Study of hydrogen bridge formation in free radical solutions via dynamic nuclear polarization
✍ Scribed by Müller-Warmuth, W.; Öztekin, Erol
- Book ID
- 115527511
- Publisher
- Taylor and Francis Group
- Year
- 1969
- Tongue
- English
- Weight
- 180 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0026-8976
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In contrast to previously studied nuclei, solvent carbon-13 NhfR enhancements at 74 G for a series of free radicals show increased contribution of scalar coupling for well shielded, saturated carbons. Enriched \*'CC4 with BDPA gives an ultimrtte enhancement of +850.
## Abstract Geometric isomerizations of olefins following photoinduced electron transfer (PET) are classified according to the relative energetic positions of the radical‐ion pairs and the reactant triplets. Each class exhibits characteristic CIDNP (chemically induced dynamic nuclear polarization)