Study of energy distribution of active sites in heterogeneous Ziegler-Natta catalysts
β Scribed by Lyudmila A. Novokshonova; Natalia Yu. Kovaleva; Yurii A. Gavrilov; Vadim G. Krasheninnikov; Ilia O. Leipunskii; Alexey N. Zhigach; Michail N. Larichev; Michail V. Chebunin
- Book ID
- 106002193
- Publisher
- Springer
- Year
- 1997
- Tongue
- English
- Weight
- 491 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0170-0839
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## Abstract Poly(propylene) samples produced by heterogeneous ZieglerβNatta catalysts containing different internal electron donors were fractionated by using temperature rising elution fractionation; some key fractions were analyzed with ^13^C NMR. It was found that internal electron donors with d
Polypropylene (PP) prepared with the MgC1z/TiC1,-A1Et3/PhzSi(OMe)2 catalyst system was fractionated by a preparative temperature rising elution fractionation (TREF) technique in the wide temperature range of room temperature to 13OoC. The results of fractionation showed that there were plural active