Study of complex formation between lead(II) acetate andmeso-tetraphenylporphin
β Scribed by O. V. Molodkina; T. N. Lomova; E. G. Mozhzhukhina
- Book ID
- 105595169
- Publisher
- Springer
- Year
- 1998
- Tongue
- English
- Weight
- 460 KB
- Volume
- 47
- Category
- Article
- ISSN
- 1573-9171
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π SIMILAR VOLUMES
The complex, bis(2,2'-bipyridine)-bis-cyanoruthenium(II), (D), forms three detectable ground-state complexes with silver(I): DAg +, D2Ag +, and DAg~ +. The first, DAg Γ·, is isolable and strongly luminescent. Both DAg +\* and the oxidized complex, DAg 2+, are stable during photochemical experiments.
## Catalytic activity of [ ( $-C5Hs) (PPh,),RuX] (X = Cl ( 1), SnF, (2) ) was investigated for the highly selective formation of methyl acetate with methanol used as the sole source. Complex 2 was found to be more catalytically active than the singlemetallic complex 1. For both complexes, the init