✦ LIBER ✦

Studies with a Single-Pulse Shock Tube. III. The Thermal Isomerization of Methyl Isocyanide

✍ Scribed by Lifshitz, Assa.; Carroll, H. F.; Bauer, S. H.

Book ID: 127093294
Publisher: American Chemical Society
Year: 1964
Tongue: English
Weight: 507 KB
Volume: 86
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja01062a006

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Single pulse shock tube study on the the

Single pulse shock tube study on the thermal stability of ketones

✍ Wing Tsang 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 English ⚖ 611 KB

5-Methyl-hexanone-2, 3-methyl-pentanone-2, and hexanone-2 have been decomposed in comparative rate single pulse shock tube experiments. The mechanism of decomposition involves the breaking of carbon-carbon bonds as well as molecular processes involving 6-center complexes. The following rate expressi

Single-pulse shock tube studies on the k

Single-pulse shock tube studies on the kinetics of the thermal decomposition of methane

✍ G.I. Kozlov; V.G. Knorre 📂 Article 📅 1962 🏛 Elsevier Science 🌐 English ⚖ 796 KB

Rate and mechanism of thermal decomposit

Rate and mechanism of thermal decomposition of 4-methyl-l-pentyne in a single-pulse shock tube

✍ Wing Tsang 📂 Article 📅 1970 🏛 John Wiley and Sons 🌐 English ⚖ 568 KB

Dilute mixtures of 4-methyl-1 -pentyne have been pyrolyzed in a single-pulse shock tube. The decomposition process involves bond breaking : kn HC=C--CH2(i-C3H7) --+ HC=zC-<:H2.(propyny1) + i-C,H,as nr1I as a molecular reaction: HC=C-CH,(i-C,H,) % C,H4(allene) + C,H, . The rate parameters are: k B -k

Kinetics of the thermal decomposition of

Kinetics of the thermal decomposition of CF3CHCL2 in a single-pulse shock tube

✍ M. V. C. Sekhar; G. E. Millward; E. Tschuikow-Roux 📂 Article 📅 1973 🏛 John Wiley and Sons 🌐 English ⚖ 496 KB

The pyrolysis of 2,2-dichloro-l , 1 ,I-trifluoroethane was studied over the temperature range of 112(tI26OoK at total reflected shock pressures from -2800 to 3100 torr. Below 1260"K, the decomposition leads to three reaction products which were identified as CF&FCI, CF&FH, and CF3CC13. The results a

The methyl isocyanide isomerization: A C

The methyl isocyanide isomerization: A CNDO/2 study with partitioning of energy

✍ J. B. Moffat; K. F. Tang 📂 Article 📅 1973 🏛 Springer 🌐 English ⚖ 615 KB

Comparative rate single-pulse shock tube

Comparative rate single-pulse shock tube studies on the thermal decomposition of cyclohexene, 2,2,3-trimethylbutane, isopropyl bromide, and ethylcyclobutane

✍ Wing Tsang 📂 Article 📅 1970 🏛 John Wiley and Sons 🌐 English ⚖ 630 KB

## Abstract A check of the data from comparative rate single‐pulse shock tube experiments have been carried out through the use of a new standard reaction, the decyclization reaction of ethylcyclobutane. The rate expressions for cyclohexene and 2,2,3‐trimethylbutane have been found to be in excel