𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Studies towards the total synthesis of methyl isosartortuoate: enantioselective synthesis of a precursor of the macrocycle

✍ Scribed by Xibin Liao; Xingxiang Xu

Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
146 KB
Volume
41
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

A concise synthesis of a precursor of dienyl cembranoids starting from geraniol is reported. All of the four chiral centers in the dienyl unit were established by Sharpless kinetic resolution, asymmetric epoxidation and dihydroxylation.

πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: Studies Towards the
ChemInform Abstract: Studies Towards the Total Synthesis of Methyl Isosartortuoate: Enantioselective Synthesis of a Precursor of the Macrocycle.
✍ Xibin Liao; Xingxiang Xu πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 25 KB πŸ‘ 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v

Studies towards the synthesis of neopelt
Studies towards the synthesis of neopeltolide: synthesis of a ring-closing metathesis macrocyclization precursor
✍ Gordon J. Florence; Romain F. Cadou πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 French βš– 445 KB

An advanced ring-closing metathesis precursor for the synthesis of the marine macrolide neopeltolide is prepared in a stereocontrolled manner by the coupling of the C2-C10 and C11-C16 subunits. The metathesis reaction of 4 with Grubbs' II or Nolan's indenylidene catalyst led to the unexpected format