๐”– Bobbio Scriptorium
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Studies on the Reversal of the Mannich Reaction

โœ Scribed by Kun, Kenneth A.; Spoerri, Paul E.


Book ID
118228186
Publisher
American Chemical Society
Year
1955
Tongue
English
Weight
436 KB
Volume
77
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES


OBSERVATIONS ON THE MANNICH REACTION
โœ FRY, EDWARD M. ๐Ÿ“‚ Article ๐Ÿ“… 1945 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 298 KB
Reverse Mannich reaction of some 5-hydro
โœ Monti, Stephen A.; Castillo, Gabriel D. ๐Ÿ“‚ Article ๐Ÿ“… 1970 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 529 KB

The C4-dimethylaminomethyl Mannich adducts of 3-substituted 5-hydroxyindoles undergo a facile, amine catalyzed carbon-carbon bond cleavage to yield the corresponding Ca-hydrogen indole derivatives. Reverse Mannich condensation occurs most readily in Cs-carbethoxy substrates, then in &ethyl derivativ