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Studies on the molecular toxicology of buta-1,3-diene and isoprene epoxides

✍ Scribed by Christine Bleasdale; Rowena D. Small; William P. Watson; Joanne Wilson; Bernard T. Golding

Book ID
103657988
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
255 KB
Volume
113
Category
Article
ISSN
0300-483X

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Addition of lithium metal to but-1-en-3-ynes. Synthesis and epoxidation of 1,4-bis(trimethylsilyl)buta-1,2-dienes
✍ Christiane Santelli-Rouvier; Sophie LefrΓ¨re; Maurice Santelli πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 234 KB

But-1-en-3-ynes react with lithium and chlorotrimethylsilane in THF to give 1,4-bis(trimethylsilyl)buta-2,3dienes. Epoxidation of these allenes leads to oxyallyl species which are trapped by nucleophilic reagents to give 1,4-bis(trimethylsilyl)butan-3-ol-2-one derivatives.