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172. The thermal co-dimerisation of isoprene and buta-1,3-diene

✍ Scribed by Johnstone, R. A. W. ;Quan, P. M.


Book ID
120544359
Publisher
The Royal Society of Chemistry
Year
1963
Weight
354 KB
Category
Article
ISSN
0368-1769

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The thermal unimolecular isomerization o
✍ H. E. O'Neal; H. M. Frey πŸ“‚ Article πŸ“… 1970 πŸ› John Wiley and Sons 🌐 English βš– 230 KB

## Abstract The reversible isomerization of __cis__‐hepta‐1,3‐diene to __cis__‐2‐__trans__‐4‐heptadiene via a 1,5 hydrogen shift has been investigated kinetically at nine temperatures in the range of 475Β° to 531Β°K. Equilibrium is reached near 94% reaction. Some __cis__‐2‐__cis__‐4‐heptadiene is als