Studies on the Mechanism of the Excitation Step in Peroxyoxalate Chemiluminescence
✍ Scribed by Stevani, Cassius V.; Silva, Sandra M.; Baader, Wilhelm J.
- Book ID
- 120240695
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 445 KB
- Volume
- 2000
- Category
- Article
- ISSN
- 1434-193X
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📜 SIMILAR VOLUMES
Several analytes such as the inorganic anions bromide, iodide, sulphite and nitrite and organic compounds as substituted anilines and sulphur compounds cause quenching of peroxyoxalate chemiluminescence. A detection method for liquid chromatography based on the quenching phenomenon has been develope
The peroxyoxalate system undergoes one of the most efficient chemiluminescence reactions and is the only one considered to involve an intermolecular chemically initiated electron exchange luminescence mechanism, with proven high efficiency. Several reactive intermediates have been proposed, which, u