Studies on the mechanism of experimental porphyria and ferrochelatase inhibition produced by 3,5-diethoxycarbonyl-1,4-dihydrocollidine
β Scribed by T.R. Tephly; A.H. Gibbs; G. Ingall; F. De Matteis
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 639 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0020-711X
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R 2 PC1 2-Benzylthio -4,5 -benzo-1,3,2-dioxaphospholane reacts with oxygen to form the corresponding thiophosphonate, dithiophosphate and pyrophosphite. The reaction was found to be of a radical nature. The mechanism is suggested to i n m l w an initial electron transfer with suitable subsequent tra
## Abstract The new ligand bdip (=2β(1,3βbenzodioxolβ4βyl)β1__H__βimidazo[4,5β__f__][1,10]phenanthroline) and its Ru^II^ complexes [Ru(4,7βdmp)~2~(bdip)]^2+^ (**1**; 4,7βdmp=4,7βdimethylβ1,10βphenanthroline) and [Ru(bpy)~2~(bdip)]^2+^ (**2**; bpy=2,2β²βbipyridine) were synthesized and characterized