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Studies on the Mechanism of Clemmensen Reduction. II. Evidence for the Formation of an Intermediate Carbonium Ion

✍ Scribed by Nakabayashi, Tadaaki


Book ID
125999619
Publisher
American Chemical Society
Year
1960
Tongue
English
Weight
397 KB
Volume
82
Category
Article
ISSN
0002-7863

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## Abstract In __m__‐nitrobenzaldoxime a strongly enhanced loss of OHβ‹… is observed as compared with the p‐nitro compound. Evidence is presented for a fragmentation mechanism involving the formation of a cyclohexadiene‐type intermediate ion formed by a rearrangement of the hydroxyl hydrogen to the p