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On the formation of the [M OH]+ ion in m-nitrobenzaldoxime. evidence for a cyclohexadiene-type intermediate ion

✍ Scribed by Peter C. Vijfhuizen; Wim Verboom; Wigger Heerma

Publisher
John Wiley and Sons
Year
1976
Tongue
English
Weight
227 KB
Volume
11
Category
Article
ISSN
1076-5174

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✦ Synopsis

Abstract

In m‐nitrobenzaldoxime a strongly enhanced loss of OHβ‹… is observed as compared with the p‐nitro compound. Evidence is presented for a fragmentation mechanism involving the formation of a cyclohexadiene‐type intermediate ion formed by a rearrangement of the hydroxyl hydrogen to the phenyl ring.

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