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Studies on the isomerization of substituted allyl alcohols over Raney nickel

✍ Scribed by J.V.N.Vara Prasad; C.N. Pillai

Book ID
113177349
Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
364 KB
Volume
88
Category
Article
ISSN
0021-9517

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Experimental and theoretical studies on
Experimental and theoretical studies on the isomerization of allyl thiocyanate to allyl isothiocyanate
✍ M. Kotani; Y. Shigetomi; M. Imada; M. Ōki; M. Nagaoka πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 231 KB πŸ‘ 2 views

The mechanism of isomerization of allyl thiocyanate to allyl isothiocyanate has been investigated both experimentally and theoretically. The kinetic study indicates that the reaction is unimolecular and is not ionic. The entropy of activation suggests strongly that the mechanism involves a cyclic tr