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Studies on the Grignard Reaction-VI. Steric Effects in the Grignard Addition Reaction on Ketones

✍ Scribed by J. van Schoote; M. Anteunis

Publisher: Wiley (John Wiley & Sons)
Year: 2010
Weight: 132 KB
Volume: 72
Category: Article
ISSN: 0037-9646
DOI: 10.1002/bscb.19630721113

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✦ Synopsis

Abstract

The reactivity in the normal Grignard addition reaction is greatly reduced when the ketone is branched in the α‐position. Alkylation in β‐position has only slight effect and in the γ‐position there is no effect at all.

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