Studies on the Decomposition of Alkyl Hydroperoxides by different catalysts
β Scribed by Gerlinde Lauterbach; Prof. Dr. W. Pritzkow; Dr. Tieu Dung Tien; Dr. V. Voerckel
- Publisher
- John Wiley and Sons
- Year
- 1988
- Tongue
- English
- Weight
- 819 KB
- Volume
- 330
- Category
- Article
- ISSN
- 1615-4150
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π SIMILAR VOLUMES
## Abstract During the thermal decomposition of cumene hydroperoxide at about 125Β°C in phenyl cycloalkanes as solvents, the solvents are attacked, preferably at the tertiary Cο£ΏH bonds. Up to 70% (with regard to the decomposed hydroperoxide) of oxidation products of the phenyl cycloalkanes are obtai
In the ferrous ion induced decomposition of alkyl hydroperoxides in the presence of cupric halides or pseudohalides, intramolecular functionalization, with ligand transfer from cupric salts to S-carbon atom, is achieved. Alkoxy radicals containing more than four carbon atoms in an alkyl chain, gener
The chromium oxide-catalyzed oxidation of allylic alcohols -RIcH(OH)CR2=CItR 3 -by ROOH (R= t-Bu, PhCMe2) affords generally a mixture of RIcocR2=CItR 3 and RIcH=CR2COR 3. The rate of the reaction and the ratio between the two oxidized compounds both depend on the nature of R. It has been concluded t