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Homogeneous chromium(VI)-catalyzed oxidations of allylic alcohols by alkyl hydroperoxides: Influence of the nature of the alkyl group on the product distribution

✍ Scribed by Abdelkhalek Riahi; Françoise Hénin; Jacques Muzart

Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
293 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis

The chromium oxide-catalyzed oxidation of allylic alcohols -RIcH(OH)CR2=CItR 3 -by ROOH (R= t-Bu, PhCMe2) affords generally a mixture of RIcocR2=CItR 3 and RIcH=CR2COR 3. The rate of the reaction and the ratio between the two oxidized compounds both depend on the nature of R. It has been concluded that the oxidative species and the reactive intermediates c(mtain this R group.

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