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Studies on the Cationic Copolymerization of α-Pinene and Styrene with Complex SbCl 3 /AlCl 3 Catalyst Systems. I. Effects of the Polymerization Conditions on the Copolymerization Products

✍ Scribed by Deng, Yunxiang; Peng, Chaopan; Liu, Ping; Lu, Jiang; Zeng, Longmei; Wang, Lichang


Book ID
121372245
Publisher
Taylor and Francis Group
Year
1996
Tongue
English
Weight
491 KB
Volume
33
Category
Article
ISSN
1060-1325

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The main kinetic laws governing 4-methylpentene-I (MP) polymerization and copolymerization with propylene (P) on the catalytic system TiCI 3 + (C2Hs)gAIC1 between 30 and 70 ° were studied. The MP homopolymerization is kinetically first-order in monomer and TiCl> The effective activation energy is 8'