The radical polymerizations of acrylamide and methacrylamide and of acrylic, methacrylic and fluoroacrylic acids have been studied in various solvents. The nature of the solvent affects the overall rate due to changes in kp and Ep. It has been shown that the effect of solvent also depends on the nat
Studies on radiation polymerization in solution: III. Effect of primary radicals in the termination reaction
β Scribed by S. Okamura; T. Manabe
- Publisher
- Elsevier Science
- Year
- 1961
- Tongue
- English
- Weight
- 507 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0032-3861
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Acrylamide was polymerized in acetonitrile at 82 Β°C with a perfluorinated azo-derivative initiator. The polymerization proceeded heterogeneously. Varying amounts of initiator and monomer were used. The activation energy was deduced from three experiments carried out at 59, 71, and 82 Β°C. The followi