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Effect of solvent on chain propagation and termination reaction rates in radical polymerization

✍ Scribed by V.F. Gromov; N.I. Galperina; T.O. Osmanov; P.M. Khomikovskii; A.D. Abkin

Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
543 KB
Volume
16
Category
Article
ISSN
0014-3057

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✦ Synopsis

The radical polymerizations of acrylamide and methacrylamide and of acrylic, methacrylic and fluoroacrylic acids have been studied in various solvents. The nature of the solvent affects the overall rate due to changes in kp and Ep. It has been shown that the effect of solvent also depends on the nature of the monomer. A possible explanation of the observed behaviour is discussed. * DO---xlioxane.

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