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Studies on Hydrozirconation of 1-Alkynyl Sulfoxides or Sulfones and the Application for the Synthesis of Stereodefined Vinyl Sulfoxides or Sulfones

✍ Scribed by Huang, Xian; Duan, Dehui; Zheng, Weixin


Book ID
127140527
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
126 KB
Volume
68
Category
Article
ISSN
0022-3263

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## Abstract The oxidation of the __trans,cis__‐(**2**) and __trans,trans__‐epoxides (**3**) of differently substituted (__Z__)‐3‐arylidene‐1‐thioflavan‐4‐ones (**1**) with dimethyldioxirane (DMD) yielded the appropriate sulfoxides (**4, 5**) and sulfones (**6, 7**). The structures were elucidated b