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Studies on Hydrozirconation of 1-Alkynyl Sulfoxides or Sulfones and the Application for the Synthesis of Stereodefined Vinyl Sulfoxides or Sulfones.

✍ Scribed by Xian Huang; Dehui Duan; Weixin Zheng


Publisher
John Wiley and Sons
Year
2003
Weight
219 KB
Volume
34
Category
Article
ISSN
0931-7597

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## Abstract The oxidation of the __trans,cis__‐(**2**) and __trans,trans__‐epoxides (**3**) of differently substituted (__Z__)‐3‐arylidene‐1‐thioflavan‐4‐ones (**1**) with dimethyldioxirane (DMD) yielded the appropriate sulfoxides (**4, 5**) and sulfones (**6, 7**). The structures were elucidated b