𝔖 Bobbio Scriptorium
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Studies on heat-resistant thermosetting phthalocyanine polymers

✍ Scribed by B. N. Achar; G. M. Fohlen; J. A. Parker

Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
391 KB
Volume
29
Category
Article
ISSN
0021-8995

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✦ Synopsis

New thermosetting poly(copper phthalocyanine) imide polymers with good toughness, superior thermal stability, chemical inertness, and fire resistance characteristics have been prepared. The studies of polymerization of two bisphthalonitriles were made using metal powder or metallic salt. Infrared, differential scanning calorimetry and thermogravimetric studies were used in determining the optimum conditions for polymerization and in characterizing the polymers produced. These polymers are noteworthy for their high char yield (73-76%) at 800°C in nitrogen atmosphere. These phthalocyanine, imide-thermosetting polymers are expected to be useful in preparing heat-resistant molded articles or laminates.

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