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Preparation of heat-resistant gradient-index polymer optical fiber rods based on poly(N-isopropylmaleimide-co-methyl methacrylate)

✍ Scribed by Dong-Jun Wang; Chen-Bin Gu; Peng-Lei Chen; Shi-Xiong Liu; Zhen Zhen; Jian-Cheng Zhang; Xin-Hou Liu


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
65 KB
Volume
87
Category
Article
ISSN
0021-8995

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✦ Synopsis


Abstract

Using the interfacial gel polymerization method, a heat‐resistant gradient‐index polymer optical fiber (GI POF) was developed based on the copolymer of methyl methacrylate (MMA) and N‐isopropylmaleimide (IPMI) as the matrix material and bromobenzene (BB) as dopant. The gradient distribution of IPMI in the GI POF rod was determined by element analysis. IPMI had great advantage in improving glass transition temperature (T~g~) and forming a gradient‐index profile. There was a significant enhancement in the heat‐resistant property in comparison with a conventional GI POF rod. The combination of high thermal stability and easy fabrication makes the novel BB–IPMI–MMA system very suitable for heat‐resistant GI POF. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 280–283, 2003