𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Studies on Grignard reagents. Part III. Proton resonance spectra of alkyl and aryl Grignard reagents

✍ Scribed by Evans, D. F.; Fazakerley, G. V.

Book ID
121403287
Publisher
The Royal Society of Chemistry
Year
1971
Weight
605 KB
Category
Article
ISSN
0022-4944

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Low Temperature Studies of Iron-Catalyze
Low Temperature Studies of Iron-Catalyzed Cross-Coupling of Alkyl Grignard Reagents with Aryl Electrophiles
✍ Jonatan Kleimark; Per-Fredrik Larsson; Parisa Emamy; Anna HedstrΓΆm; Per-Ola Norr πŸ“‚ Article πŸ“… 2012 πŸ› John Wiley and Sons 🌐 English βš– 441 KB πŸ‘ 2 views

## Abstract The title reaction has been studied under low temperature conditions. Coupling with active substrates can be done even at dry ice temperature. Initial rate studies at βˆ’25 °C indicate that high concentrations of any reagent can lead to either complete or partial catalyst deactivation. Un

1H nuclear magnetic resonance studies of
1H nuclear magnetic resonance studies of the reaction of iron(III) porphyrin cation radical with aryl Grignard reagents
✍ Piotr J. Chmielewski; Lechoslaw Latos-graΕΌyΕ„ski; Krystyna Rachlewicz πŸ“‚ Article πŸ“… 1993 πŸ› John Wiley and Sons 🌐 English βš– 583 KB

## Abstract Addition of aryl Grignard reagents to an iron(III) tetraphenylporphyrin Ο€ cation radical, [(TPPβ‹…)Fe^III^Cl] (SbCl~6~), in dichloromethane solution at 202 K yields a mixture of σ‐phenyl iron(IV) tetraphenylporphyrin, [(TPP)Fe^IV^(Ph)] (SbCl~6~), and σ‐phenyl iron(III) tetraphenylporphyri