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Studies on Grignard reagents. Part I. Fluorine nuclear magnetic resonance spectra of fluoroaryl Grignard reagents

✍ Scribed by Evans, D. F.; Khan, M. S.

Book ID
121449973
Publisher
The Royal Society of Chemistry
Year
1967
Weight
619 KB
Category
Article
ISSN
0022-4944

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πŸ“œ SIMILAR VOLUMES

1H nuclear magnetic resonance studies of
1H nuclear magnetic resonance studies of the reaction of iron(III) porphyrin cation radical with aryl Grignard reagents
✍ Piotr J. Chmielewski; Lechoslaw Latos-graΕΌyΕ„ski; Krystyna Rachlewicz πŸ“‚ Article πŸ“… 1993 πŸ› John Wiley and Sons 🌐 English βš– 583 KB

## Abstract Addition of aryl Grignard reagents to an iron(III) tetraphenylporphyrin Ο€ cation radical, [(TPPβ‹…)Fe^III^Cl] (SbCl~6~), in dichloromethane solution at 202 K yields a mixture of σ‐phenyl iron(IV) tetraphenylporphyrin, [(TPP)Fe^IV^(Ph)] (SbCl~6~), and σ‐phenyl iron(III) tetraphenylporphyri