𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Studies on cyclohexane derivatives: I. A chemical proof of the configuration of the two 1,4-dimethyl-cyclohexanes

✍ Scribed by H. van Bekkum; A. A. B. Kleis; A. A. Massier; P. E. Verkade; B. M. Wepster

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
415 KB
Volume
80
Category
Article
ISSN
0165-0513

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Starting from cis‐ and trans‐cyclohexane‐1,4‐dicarboxylic acid, cis‐and trans‐1,4‐dimethylcyclohexane are prepared in a way that leaves no doubt as to the configuration of the latter compounds.

📜 SIMILAR VOLUMES

Studies on cyclohexane derivatives: III.
Studies on cyclohexane derivatives: III. A chemical proof of the configurations of the two 1-isopropyl-4-methylcyclohexanes (para-menthanes)
✍ H. van Bekkum; D. Medema; P. E. Verkade; B. M. Wepster 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 380 KB

## Abstract The configurations of the two 1‐isopropyl‐4‐methylcyclohexanes (__para__‐menthanes) were determined by means of syntheses starting from pure __cis__‐and pure __trans__‐4‐methylcyclohexanecarboxylic acid.

Studies on cyclohexane derivatives: II.
Studies on cyclohexane derivatives: II. Preparation and chemical proof of the configuration of the two 4-methylcyclohexanecarboxylic acids
✍ H. van Bekkum; A. A. B. Kleis; A. A. Massier; D. Medema; P. E. Verkade; B. M. We 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 777 KB

## Abstract The preparation of pure low‐melting 4‐methylcyclohexanecarboxylic acid (m.p. 30.5‐31.5°) is described for the first time. By chemical means it is proved that low‐melting 4‐methylcyclohexanecarboxylic acid possesses the __cis__‐configuration and the high‐melting isomer the __trans__‐con

Studies on cyclohexane derivatives: IV P
Studies on cyclohexane derivatives: IV Preparation and chemical proof of the configurations of the two 4-isopropylcyclohexanecarboxylic acids
✍ H. van Bekkum; A. A. B. Kleis; D. Medema; P. E. Verkade; B. M. Wepster 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 487 KB

## Abstract The preparation of pure low‐melting 4‐isopropylcyclohexanecarboxylic acid (m.p. 40–41°) is described for the first time. It was isolated from mixtures of the low‐melting and the high‐melting isomer, making use of the fact that only the latter gives an inclusion compound with thiourea.

C-13 NMR study on configurations of disu
C-13 NMR study on configurations of disubstituted cyclohexanone and cyclohexane derived therefrom by the Huang-Minlon process
✍ Naoji Matsumoto; Ju Kumanotani 📂 Article 📅 1975 🏛 Elsevier Science 🌐 French ⚖ 179 KB

During a study of the motion of rings involved in polymer main chains, we were forced to reveal the configurations of dimethyl cyclohexanone-2,6dipropionate (k) and diethyl cyclohexane-1,3-dipropionate (2). According to the method of Stork et al. 1) Q) was prepared, from which (2) was derived by the

Physico-chemical study of the ternary sy
Physico-chemical study of the ternary system: isotactic polybutene-1-cyclohexane-n-propyl alcohol. Influence of molecular weight on the preferential adsorption phenomenon
✍ I. Katime; P. Garro; J.M. Teijon 📂 Article 📅 1975 🏛 Elsevier Science 🌐 English ⚖ 211 KB

This paper presents results on the influence of molecular weight on the preferential adsorption coefficient, ;,, for the ternary system: isotactic polybutene-l-cyclohexane-n-propyl alcohol. It has been found that there are two different theta points.