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Studies of the reactivity of HO2O2− with unsaturated hydroperoxides in ethanolic solutions

✍ Scribed by Michael J. Thomas; Mark W. Sutherland; Ravindra L. Arudi; Benon H.J. Bielski

Book ID
115706280
Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
353 KB
Volume
233
Category
Article
ISSN
0003-9861

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Reevaluation of the reactivity of hydrox
Reevaluation of the reactivity of hydroxylamine with O2−/HO2
✍ Benon H.J. Bielski; Ravindra L. Arudi; Diane E. Cabelli; Wolf Bors 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 228 KB

The reactivity of hydroxylamine with HO2/O2- radicals was studied by pulse radiolysis and stopped-flow photolysis over a pH range of 1.1-10.5. Upper limits for the rate of reaction indicate that hydroxylamine, if it reacts at all, reacts at a very slow rate. Its use as an indicator for O-2 and an as