STUDIES OF THE PHOSPHORYLATION OF DIMETHYLANILINE WITH PHOSPHORUS TRICHLORIDE AND PHOSPHORUS OXYCHLORIDE 1
โ Scribed by ROBINS, ROLAND K.; CHRISTENSEN, BERT E.
- Book ID
- 127077501
- Publisher
- American Chemical Society
- Year
- 1951
- Tongue
- English
- Weight
- 267 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0022-3263
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๐ SIMILAR VOLUMES
The reaction between a" alcohol and a large excess of PC13 generally gives a dichlorophosphite, which on hydrolysis affords a phosphite. Thus, treatment of a" Ip\* ribonucleoside with PC13 should give, after hydrolysis and de-blocking the protective group, a ribonucleoside-5'-phosphite. Contrary to
The reactions of four equivalents of heterocyclic aryllithium compounds with phosphorus trichloride or phosphorus oxychloride gave symmetrical heterocyclic biaiyls in good yields. A similar coupling was found in the reactions of three equivalents of the lithi u m compounds with thionyl chloride.