Analysis of Mixtures of White Phosphorus, Phosphorus Oxychloride, and Phosphorus Trichloride
โ Scribed by Keeler, R. A.; Anderson, C. J.; Satriana, D.
- Book ID
- 127066823
- Publisher
- American Chemical Society
- Year
- 1954
- Tongue
- English
- Weight
- 282 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0003-2700
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๐ SIMILAR VOLUMES
The reactions of four equivalents of heterocyclic aryllithium compounds with phosphorus trichloride or phosphorus oxychloride gave symmetrical heterocyclic biaiyls in good yields. A similar coupling was found in the reactions of three equivalents of the lithi u m compounds with thionyl chloride.
The creation of electronically excited species by the 193 nm excimer laser photolysis of PC& and PBr, has been studied. In addition to halogen and phosphorus atomic lines, emission is detected from highly excited states of Cl2 and Br2, respectively, formed by a two-photon process. We also observe pr