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Studies of sodium O,O-dimethylphosphorodithioate and its isomers

โœ Scribed by C.K. Tseng; James H.-H. Chan

Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
133 KB
Volume
12
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Previous studies by Kabachnik and co-workers' have shown, by the

The relative rate of reaction4 of sodium 0,0-(1) and sodium O,Sdimethylphosphorodithioate (2) (determined by allowing a mixture of the two sodium salts to compete for a deficiency of methyl iodide-d3) was determined by NMR spectrometric methods. The reaction was carried out at room temperature with deuterated methanol as solvent. It was found that 1 reacted 6.4 2 0.3 times faster than 1 (i.e. kL/kP = 6.4 2 0.3).

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