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Studies of New Indole Alkaloid Coupling Methods for the Synthesis of Haplophytine

✍ Scribed by Rege, Pankaj D.; Tian, Yuan; Corey, E. J.

Book ID
115446230
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
161 KB
Volume
8
Category
Article
ISSN
1523-7060

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Tetracycles 3b-d, having the ABCD ring substructure of Strychnos alkaIoids and a &(formvhnethvl) substituent mokcted as an oxime or hvdraxone derivative. have been p&&d-by nu&phiIic addition of the enolate of indok.a&tic ester 1 to pyridinium salts 2b-d followed by acid cyclization. The same one-pot