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Studies of lifetimes of rotationally cooled NO2 using time-resolved fluorescence excitation spectra

โœ Scribed by C.H. Chen; S.D. Kramer; D.W. Clark; M.G. Payne


Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
498 KB
Volume
65
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


A tunable. pulsed dye Iaser with output in the region of 5750 to 6000 X was used to excite rotationally cooled NO1 which was produced by expansion in conjunction with argon carrier gas through ;t supersonic nou!e. The resulting timeresoked fiuoresccnce excitation spectra were used to measure the lifetimes of various vibronic bands of NOz('Bz)-The lifetimes measured were in the region of 15 to 40 ps which were shorter than those obtained from eelI experiments. For eachindividual excitation wavelength, only a single exponential decay was observed from very early times through 2.50 ps.


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