Studies into the mechanism of the rhodium-catalyzed carbonylation of isopropyl alcohol
β Scribed by Dekleva, Thomas W.; Forster, Denis
- Book ID
- 119958908
- Publisher
- American Chemical Society
- Year
- 1985
- Tongue
- English
- Weight
- 661 KB
- Volume
- 107
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
Rhodium complexes show high activity in homogenous carbonylations of alcohols and hydrocarboxylations of alkenes to carboxylic acids in the presence of alkyl halides. Analogously to liquid phase reactions, rhodium on different supports (active carbon, zeolite, SiO2, A1203, polymers, etc.) is the mos
The effects of the presence of water on the rhodium-catalyzed carbonylation of isopropylallylamine were studied as a function of the following parameters: reaction temperature; water content; presence of phosphines; solvent polarity and presence of bulky ions. It turned out that the reaction is stro