✦ LIBER ✦

Studies in the zinc reduction series: The reduction of certain 2-benzoylbenzoic acids and esters

✍ Scribed by Gerald E. Risinger; James A. Thompson

Publisher: Elsevier Science
Year: 2010
Tongue: English
Weight: 217 KB
Volume: 82
Category: Article
ISSN: 0165-0513
DOI: 10.1002/recl.19630820809

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The reaction mechanism of the reduction o certain 2‐benzoylbenzoic acids and esters is discussed. It is suggested that the carboxyl group directs product formation either by neighboring group participation or by facilitating the hydrogenolysis of the carbinol group. Furthermore, it is concluded that the intermediate in the reduction of the esters does not contain a carbinol group.

📜 SIMILAR VOLUMES

Studies in the zinc reduction series: Re

Studies in the zinc reduction series: Relationship of zinc and acid to zinc and alkali reductions of aldehydes and ketones

✍ G. E. Risinger; J. M. Garrett; J. A. Winkler 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 161 KB

Intracellular oxidation-reduction studie

Intracellular oxidation-reduction studies. VI. The effects of penetrating and non-penetrating acids and bases on the oxidation-reduction phenomena in starfish eggs

✍ Beck, Lyle V. 📂 Article 📅 1933 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 807 KB

Kinetics of reduction, composition and t

Kinetics of reduction, composition and the stability constants of the zinc–maleic acid complexes in aqueous medium

✍ J.N. Gaur; V.K. Sharma 📂 Article 📅 1977 🏛 Elsevier Science 🌐 English ⚖ 379 KB

Akstrati-Folaarographic reduction of the zincmaleic acid complexes has beeu studied at the dropping mercury electrode (dme) in aqueous medium at ,30" and ionic strength 2.0. Gelling's method is used for determining the reversible half-wave potentials and the kinetic parameters (a and K,) for the qua

An electrochemical and optical microscop

An electrochemical and optical microscopic study of the reduction of HTeO2+ in aqueous acid solution

✍ S. Dennison; S. Webster 📂 Article 📅 1991 🏛 Elsevier Science ⚖ 888 KB

Borohydride Reduction of Acetophenone an

Borohydride Reduction of Acetophenone and Esters of Dehydrocarboxylic Acids in the Presence of Chiral Cobalt(II) Diamine Complexes.

✍ L. O. Nindakova; B. A. Shainyan 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 21 KB

Studies of reduction and reductive alkyl

Studies of reduction and reductive alkylation of coals in the potassium/liquid ammonia system. 2. Characterization of coal extracts

✍ Helena Wachowska; Mieczysław Kozłowski 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 578 KB

The products of reduction and reductive alkylation of five demineralized coals run in a system of potassium/ liquid ammonia were subject to extraction by methylene chloride and n-pentane. The paper reports infrared and nuclear magnetic resonance (n.m.r.) characteristics of the extracts and the resul