Studies in the Mechanism of the Willgerodt Reaction. II. Direction of Migration of the Functional Group in Aliphatic Ketones 1
β Scribed by Cerwonka, Edward; Anderson, R. Christian; Brown, Ellis V.
- Book ID
- 120473423
- Publisher
- American Chemical Society
- Year
- 1953
- Tongue
- English
- Weight
- 439 KB
- Volume
- 75
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
## Abstract The course of carboxyl group exchange in the thermal decomposition of a mixture of disodium adipate and pimelate has been studied using ^14^Cβlabelled compounds. The exchange data obtained from the residual acide and ketone formed point to two different incorporation processes. This phe
In the presence of trifluoroacetic anhydride or N-chlorosuccinimide, aliphatic aldehydes react with dimesitylboron stabilised carbanions to give, after work up, the corresponding ketones, a process which is unique among Wittig type reactions. Yields of ketones are satisfactory in all cases