## Abstract The carbon‐13 NMR spectra of some __N__‐(2‐ or 4‐nitrophenyl) tertiary amines and their corresponding __N__‐oxides have been analysed. These __N__‐oxides undergo thermal rearrangement to __O__‐arylhydroxylamines, for which the ^13^C NMR spectral assignments were also carried out. The __
✦ LIBER ✦
Studies in tertiary amine oxides. III—carbon-13 NMR assignment of N-alkynyl cyclic amines
✍ Scribed by Jasim M. A. Al-Rawi; Abdul-Hussain Khuthier
- Publisher
- John Wiley and Sons
- Year
- 1981
- Tongue
- English
- Weight
- 261 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
Abstract
Carbon‐13 NMR spectra of 24 N‐alkynyl cyclic amines were analysed. The effect of substituting the acetylenic proton by n‐butyl, tert‐butyl and phenyl groups was determined.
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## Abstract Carbon‐13 NMR chemical shifts and ^1^__J__(CH), ^2^__J__(CH) and ^3^__J__(CH) coupling constants of selected saturated nitrogen heterocyclic molecules containing the acetylenic moiety have been determined. These NMR parameters have also been determined for the corresponding __N__‐oxides