Studies in organosilicon chemistry XLVII. The synthesis and infrared study of heterocyclic compounds of silicon, germanium and tin
β Scribed by Francis J. Bajer; Howard W. Post
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- English
- Weight
- 345 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0022-328X
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The electron impact and chemical ionisation mass spectra of a number of organometallic derivatives of silicon, germanium, tin and lead, incorporating inter alia 2-bis(trimethylsilyl)methylpyridyl or cyclopentadienyl ligands have been recorded. Representative spectra are presented and illustrate the
## Abstract Siliconβ29, carbonβ13 and oxygenβ17 NMR data are reported for the methylethoxysilanes, Me~__n__~Si(OEt)~4β__n__~ with __n__ = C to 3. The values of ^1^__J__(SiC) vary greatly, in a manner which appears to be inconsistent with an effect of __s__βcharacter variation alone. The chemical sh