Studies in mass spectrometry. Part VIII. peri- and ortho-Effects in the mass spectra of some aromatic nitro-compounds
β Scribed by Harley-Mason, John; Toube, T. P.; Williams, D. H.
- Book ID
- 118149177
- Publisher
- Royal Society of Chemistry
- Year
- 1966
- Weight
- 560 KB
- Category
- Article
- ISSN
- 0045-6470
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π SIMILAR VOLUMES
## Abstract The appearance of [MHβ30]^+^ ions in the chemical ionization mass spectra of aromatic nitro compounds may be due to their initial reduction to the corresponding amines within the ion source. Aromatic nitroso compounds may be similarly reduced to yield [MHβ14]^+^ ions. The hydroxy deriva
New examples of the ortho effect in bisphenol A derivatives including interaction of the hydrogen of the orthohydroxy group with the neighbouring aromatic ring have been observed. The characteristic ions [ M -PhOH j +. (m/z = 134) and [ M -CH, -PhOHj + (m/z = 119) were shown to form through the hydr