✦ LIBER ✦

Anomalous ions in the chemical ionization mass spectra of aromatic nitro and nitroso compounds

✍ Scribed by Joseph J. Brophy; Vladimir Diakiw; Robert J. Goldsack; Derek Nelson; James S. Shannon

Publisher: John Wiley and Sons
Year: 1979
Tongue: English
Weight: 183 KB
Volume: 14
Category: Article
ISSN: 1076-5174
DOI: 10.1002/oms.1210140408

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✦ Synopsis

Abstract

The appearance of [MH‐30]^+^ ions in the chemical ionization mass spectra of aromatic nitro compounds may be due to their initial reduction to the corresponding amines within the ion source. Aromatic nitroso compounds may be similarly reduced to yield [MH‐14]^+^ ions. The hydroxy derivatives of the nitroso compounds yield further anomalous ions at [MH‐16]^+^ probably due to the reduction of the hydroxy groups.

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