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Studies in biomimetic alkaloid syntheses. 12. Enantioselective total syntheses of (-)- and (+)-vincadifformine and of (-)-tabersonine

โœ Scribed by Kuehne, Martin E.; Podhorez, David E.


Book ID
126974548
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
782 KB
Volume
50
Category
Article
ISSN
0022-3263

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ChemInform Abstract: Efficient Total Syn
โœ Satoshi Kobayashi; Ge Peng; Tohru Fukuyama ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 33 KB ๐Ÿ‘ 2 views

Efficient Total Syntheses of (ยฑ)-Vincadifformine and (-)-Tabersonine. -The stereocontrolled total synthesis of title compounds (IV) and (VIII) features a novel amine-protecting protocol by means of 2,4dinitrobenzenesulfonamides. This allows formation of the crucial intermediates (III) and (VI) unde