Studies in base-catalyzed allenic oxy-Cope rearrangement: an expedient synthesis of functionalized bicyclo[4.3.0] and -[4.4.0] systems and 3,5-cycloundecadien-1-one
β Scribed by Balakumar, Arumugham; Janardhanam, Selvasekaran; Rajagopalan, Krishnamoorthy
- Book ID
- 126155049
- Publisher
- American Chemical Society
- Year
- 1993
- Tongue
- English
- Weight
- 713 KB
- Volume
- 58
- Category
- Article
- ISSN
- 0022-3263
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## Abstract The kinetics of cleavage of 3βhydroxybicyclo[4.2.0]octaβ1,3,5βtrienβ7βones in aqueous sodium hydroxide, and of the alkoxy and acetoxy analogues in methanolic sodium methoxide solution, were examined under pseudoβfirstβorder reaction conditions. The dependence of the rate upon the basici