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Studies directed towards the synthesis of stevastelins—a macrolactonization approach to stevastelin B

✍ Scribed by Tushar K Chakraborty; Subhash Ghosh; Shantanu Dutta

Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
61 KB
Volume
42
Category
Article
ISSN
0040-4039

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A synthesis of the stevastelins, a novel class of immunosuppressant agents, is reported based on a macrolactonization approach. This synthesis commenced with the stereoselective preparation of the stearic acid segment from tetradecanal using Evans asymmetric synthesis methodology and an aldol reacti