✦ LIBER ✦

Studies directed toward the preparation of polyene macrolide mimics

✍ Scribed by David M. Floyd; Alan W. Fritz

Publisher: Elsevier Science
Year: 1981
Tongue: French
Weight: 230 KB
Volume: 22
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)81766-4

No coin nor oath required. For personal study only.

✦ Synopsis

Cyclodimerization of two symmetrical but dissimilar fragments provides a facile route to macrocyclic dilactones containing conjugated polyolefins. Methods have been developed for the stereoselective synthesis of cis-2,4,6-7 triacetoxyheptanedial and the simple acylation of alcohols with dimethyl phosphonoacetic acid.

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