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Studies directed toward the total synthesis of maytansine. The preparation and properties of the carbinolamide moiety.

✍ Scribed by A.I. Meyers; Chia-Cheng Shaw

Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
173 KB
Volume
15
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

Progress toward the total synthesis of m
Progress toward the total synthesis of maytansine. A stereoselective synthesis of the C-1 to C-7 moiety (northern zone)
✍ A.I. Meyers; C.C. Shaw; Deane Horne; L.M. Trefonas; R.J. Majeste πŸ“‚ Article πŸ“… 1975 πŸ› Elsevier Science 🌐 French βš– 174 KB

The complex structure of the potent anti-leukemic ansa macrolide, maytansine (3,' undoubtedly presents a formidable synthetic challenge. We have recently reported2 the preparation of the cyclic carbinolamide gwhich represents the so-called "eastern zone" of maytansine. In this communication we wis