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Struktur von Hexafulminatocobaltat(III), [Co(CNO)6]3–

✍ Scribed by Peter Mayer; Walter Ponikwar; Klaus Feldl; Peter Swoboda; Wolfgang Beck


Publisher
John Wiley and Sons
Year
2000
Tongue
German
Weight
62 KB
Volume
626
Category
Article
ISSN
0372-7874

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✦ Synopsis


Professor Max Schmidt zum 75. Geburtstag gewidmet Pseudohalogeno Metal Compounds. LXXVII [1] Structure of Hexafulminatocobaltate(III), [Co(CNO) 6 ] 3± Abstract. In the crystal of [AsPh 4 ] 3 [Co(CNO) 6 ] the hexafulminatocobaltate(III) anion forms an ideal octahedron with linear CºN±O ligands and with relatively short cobalt-carbon bonds (Co±C 191 pm). In the crystal the [AsPh 4 ] + cations ªdiluteº the energy rich anions.


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