Synthese und Struktur von [Fe6(CO)12(TePh)12]

✍ Scribed by Marco Bettenhausen; Dieter Fenske

• Publisher: John Wiley and Sons
• Year: 1999
• Tongue: German
• Weight: 70 KB
• Volume: 625
• Category: Article
• ISSN: 0372-7874
• DOI: 10.1002/(sici)1521-3749(199901)625:1<13::aid-zaac13>3.0.co;2-k

✦ Synopsis

The reaction of [Fe(CO) 4 (HgCl) 2 ] with PhTeSiMe 3 leads to the formation of red needles. [Fe 6 (CO) 12 (TePh) 12 ] was characterised by single crystal x-ray structure analysis. In this compound each iron atom is coordinated octahedrally by four l 2 -TePh groups and two terminal CO groups. The iron atoms form a six membered planar ring.