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Structures of isomeric 10b,10c-cis- and 10b,10c-trans-3a,5a,8a,10a-tetraazaperhydropyrene

✍ Scribed by Gluziński, P. ;Krajewski, J. W. ;Urbańczyk-Lipkowska, Z. ;Bleidelis, J. ;Kemme, A.


Book ID
114528930
Publisher
International Union of Crystallography
Year
1982
Weight
421 KB
Volume
38
Category
Article
ISSN
0567-7408

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The title compound was prepared as part of an effort to accomplish the first synthesis of a cis-10b,10c-dimethyl-10b,10c-dihydropyrene according to our ''tethered metacyclophane'' strategy. The 11-step synthesis starting from 2,4,6trimethylphenol had an overall yield of 4.1%. An X-ray crys- The 10b