8,16-Methano[2.2]metacyclophane-1,9-diene. A Valence Isomer of 10b,10c-Methano-cis-10b, 10c-dihydropyrene
✍ Scribed by Dr. Kazuhiro Nakasuji; Masanori Katada; Prof. Dr. Ichiro Murata
- Publisher
- John Wiley and Sons
- Year
- 1979
- Tongue
- English
- Weight
- 228 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The title compound was prepared as part of an effort to accomplish the first synthesis of a cis-10b,10c-dimethyl-10b,10c-dihydropyrene according to our ''tethered metacyclophane'' strategy. The 11-step synthesis starting from 2,4,6trimethylphenol had an overall yield of 4.1%. An X-ray crys- The 10b
## Abstract The reaction of 1,2‐(CH~2~OH)~2~‐__closo__‐1,2‐C~2~B~10~ H~10~ carborane with 2‐(aminomethyl)‐pyridine in methylene chloride at room temperature led to the partial cage degradation of the __closo__ carborane and its conversion to the __nido__ derivative. The addition of cobalt chloride